Product ID:SOLUTION SH200
MSDS Date:05/09/1987
FSC:6850
NIIN:00N047703
MSDS Number: BVBWJ

NALCO CHEMICAL COMANY

ONE NALCO CENTER
NAPERVILLE, IL 60563-1198
US

Emergency Phone: 708-920-1510(24 HOURS)

Info Phone: 708-305-1000

Cage: 89524

ONDEO NALCO COMPANY

NAPERVILLE, IL 60563-1198 US

Telephone: (630) 305-1000

Cage: 89524

METHANOL

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 70%

OSHA PEL 200PPM;250 STEL,S

ACGIH TLV: 200PPM;250 STEL,S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

DISP FACILITY). CAN BE INCINERATED I/A/W

RTECS: 9999999ZZ

CONTAMINATED SHOES AND LEATHER ITEMS.

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT)5,628 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE/SKIN: CAN CAUSE MODERATE
IRRITATION. INGEST: CAN CAUSE BLINDNESS FROM METHANOL. INHAL:
PROLONGED INHALATION OF MIST/VAPIR MAY CAUSE NAUSEA, DIZZINESS,
LT-HEAD, VOMITING OR UNCON DEPENDING O N LENGTH OF EXPOSURE AND
FIRST AID ACTION GIVEN.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:A REVIEW OF AVAILABLE DATA DOES NOT IDENTIFY
ANY SYMPTOMS FROM EXPOSURE.
Medical Cond Aggravated by Exposure:A REVIEW OF AVAILABLE DATA DOES NOT
IDENTIFY ANY WORSENING OF EXISTING CONDITIONS.

First Aid:EYES:FLUSH W/WATER FOR @ LST 15 MIN. CALL A PHYS. SKIN: WASH
THORO W/SOAP & RINSE W/WATER. CALL A PHYS. INGEST: INDUCE VOMIT.
CALL A PHYS. INHAL: REMOVE TO FRESH AIR. TREAT SYMPS. CALL A PHYS @
ONCE. NOTE TO PHYS: NO SPEC ANTIDOTE IS KNOWN. BASED ON INDIVIDUAL
RXN OF PATIENT, PHYS JUDGEMENT SHOULD BE USED TO CTL SYMPS &
CLINICAL CNDTN. CAUTION: IF UNCON, HAVING TROUBLE BRTHG/IN CONVULS,
DO(SUPDAT)

Flash Point Method:CC
Flash Point:70.0F,21.1C
Extinguishing Media:BASED ON NFPA GUIDE, USE DRY CHEM, ALCOHOL FOAM,
CARBON DIOXIDE/OTHER EXTING AGENT SUITABLE FOR CLASS B FIRES.
(SUPDAT)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . USE WATER TO COOL CONTAINERS EXPOSED TO
FIRE.
Unusual Fire/Explosion Hazard:TREAT LIKE A FLAMMABLE LIQUID.

Spill Release Procedures:SM LIQ SPILLS:CNTN W/ABSORB MATL, SUCH AS SAW
DUST, CLAY, SOIL/ANY COMMERCIALLY AVAL ABSORB. SHOVEL RECLAIMED LIQ
& ABSORBENT INTO RECOVERY/SALVAGE DRUMS FOR DISP. REFER TO CERCLA.
KEEP SPILL AWAY FRO M HEAT, SPARKS, FLAMES & WELD OPERATIONS.
(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:FLAMM. CNTNS METHANOL. MAY CAUSE
BLINDNESS IF SWALLOWED. MAY CAUSE IRRIT TO SKIN & EYES. DO NOT USE,
STORE, SPILL/POUR NEAR HEAT, SPARKS/OPEN FLAME.
Other Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. USE W/ADEQ
VENT. DO NOT TAKE INTERNALLY. AVOID PRLNGD & RPTD BRTHG OF VAP.
AVOID CONT W/SKIN, EYES & CLTHG. EMPTY CONTRS MAY CNTN RESIDUAL
PROD. DO NOT REUSE CON TR UNLESS PROPERLY RECONDITIONED.

Respiratory Protection:IF IT IS POSS TO GENERATE SIGNIFICANT LEVELS OF
VAPS/MISTS, A NIOSH/MSHA APPRVD/EQUIV ORG VAP CARTDG RESP IS
RECOMM.FOR LG SPILLS, ENTRY INTO LG TANKS, VESSELS/ENCLSD SM SPACES
W/INADEQ VENT, A NIOSH/ MSHA APPRVD PRESS-DEMAND, SCBA IS RECOM.
Ventilation:GENERAL VENT IS RECOMM. ADDITIONALLY, LOC EXHST VENT IS
RECOMM WHERE VAPS, MISTS/AEROSOLS MAY BE RELEASED.
Protective Gloves:IMPERMEABLE GLOVES.
Eye Protection:ANSI APPVD CHEMICAL WORK GOGG .
Other Protective Equipment:SHOES.
Work Hygienic Practices:IF CLTHG IS CONTAMD, REMOVE CLTHG & THORO WASH
AFFECTED AREA. LAUNDER CONTAMD CLTHG BEFORE REUSE. DISCARD (ING 3)
Supplemental Safety and Health
EXTING MEDIA: FOR LG FIRES, USE WATER SPRAY/FOG, THORO DRENCHING
BURNING MATL. MATL TO AVOID: WHICH CAN GENERATE HEAT, FIRES, EXPLO
& REL OF TOX FUMES. FIRST AID PROC: NOT INDUCE VOMIT/GIVE WATER.
SPI LL PROC: VENT AREA & EVAC EMPLOYEES FROM EXPOS IF AIRBORNE CONC
EXCEEDS TLV.

HCC:F3
Solubility in Water:COMPLETELY
Appearance and Odor:COLORLESS LIQUID

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS (EG. CHLORINE, PEROXIDES, CHROMATES, NITRIC ACID,
PERCHLORATES, CONC OXYGEN, PERMANGANATES), (SUPDAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:IN EVENT OF COMBUSTION CO, CO*2 MAY BE
FORMED.

Waste Disposal Methods:IF PROD BECOMES A WASTE, IT MEETS CRITERIA OF A
HAZ WASTE AS DEFINED UNDER RESOURCES CONSERVATION & RECOVERY ACT
(RCRA) 40CFR261. HAZ WASTE D001. AS A HAZ LIQ WASTE, IT MUST BE
SOLIDIFIED BEFORE DISP IN A LANDFILL (HAZ WASTE TRTMT, STOR & (ING
2)

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